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A vibrational spectroscopic study of a hydrated hydroxy-phosphate mineral fluellite, Al2(PO4)F2(OH)·7H2O.
Cejka, Jirí; Sejkora, Jirí; Macek, Ivo; Frost, Ray L; López, Andrés; Scholz, Ricardo; Xi, Yunfei.
Afiliación
  • Cejka J; Department of Mineralogy and Petrology, National Museum, Cirkusová 1740, CZ-193 00 Praha 9, Czech Republic; School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia.
  • Sejkora J; Department of Mineralogy and Petrology, National Museum, Cirkusová 1740, CZ-193 00 Praha 9, Czech Republic.
  • Macek I; Department of Mineralogy and Petrology, National Museum, Cirkusová 1740, CZ-193 00 Praha 9, Czech Republic.
  • Frost RL; School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia. Electronic address: r.frost@qut.edu.au.
  • López A; School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia.
  • Scholz R; Geology Department, School of Mines, Federal University of Ouro Preto, Campus Morro do Cruzeiro, Ouro Preto, MG 35400-00, Brazil.
  • Xi Y; School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia.
Spectrochim Acta A Mol Biomol Spectrosc ; 126: 157-63, 2014 May 21.
Article en En | MEDLINE | ID: mdl-24594888
ABSTRACT
Raman and infrared spectra of two well-defined fluellite samples, Al2(PO4)F2(OH)·7H2O, from the Krásno near Horní Slavkov (Czech Republic) and Kapunda, South Australia (Australia) were studied and tentatively interpreted. Observed bands were assigned to the stretching and bending vibrations of phosphate tetrahedra, aluminum oxide/hydroxide/fluoride octahedra, water molecules and hydroxyl ions. Approximate O-H⋅⋅⋅O hydrogen bond lengths were inferred from the Raman and infrared spectra.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Minerales Idioma: En Revista: Spectrochim Acta A Mol Biomol Spectrosc Asunto de la revista: BIOLOGIA MOLECULAR Año: 2014 Tipo del documento: Article País de afiliación: Australia

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Minerales Idioma: En Revista: Spectrochim Acta A Mol Biomol Spectrosc Asunto de la revista: BIOLOGIA MOLECULAR Año: 2014 Tipo del documento: Article País de afiliación: Australia