Hydrogen from formic acid through its selective disproportionation over sodium germanate--a non-transition-metal catalysis system.
Angew Chem Int Ed Engl
; 53(42): 11275-9, 2014 Oct 13.
Article
en En
| MEDLINE
| ID: mdl-25169798
ABSTRACT
A robust catalyst for the selective dehydrogenation of formic acid to liberate hydrogen gas has been designed computationally, and also successfully demonstrated experimentally. This is the first such catalyst not based on transition metals, and it exhibits very encouraging performance. It represents an important step towards the use of renewable formic acid as a hydrogen-storage and transport vector in fuel and energy applications.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Formiatos
/
Germanio
/
Hidrógeno
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2014
Tipo del documento:
Article
Pais de publicación:
ALEMANHA
/
ALEMANIA
/
DE
/
DEUSTCHLAND
/
GERMANY