Introducing a new radical trifluoromethylation reagent.
Chem Commun (Camb)
; 51(27): 5967-70, 2015 Apr 07.
Article
en En
| MEDLINE
| ID: mdl-25736068
ABSTRACT
Perfluoro-3-ethyl-2,4-dimethyl-3-pentyl radical (PPFR) is a persistent radical stable at room temperature, but easily decomposes at 90 °C to produce a CF3 radical which is able to react with a variety of aromatic compounds to afford the corresponding trifluoromethyl derivatives, usually as mixtures of regioisomers in good to excellent overall yields.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Radicales Libres
/
Hidrocarburos Fluorados
/
Indicadores y Reactivos
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2015
Tipo del documento:
Article
País de afiliación:
Japón