Crystal structure of bis-(cyclo-hexyl-ammonium) di-phenyl-dioxalatostannate(IV).
Acta Crystallogr E Crystallogr Commun
; 71(Pt 2): 151-3, 2015 Feb 01.
Article
en En
| MEDLINE
| ID: mdl-25878805
ABSTRACT
Reaction of oxalic acid and di-phenyl-tin dichloride in the presence of cyclo-hexyl-amine led to the formation of the title salt, (C6H14N)2[Sn(C6H5)2(C2O4)2]. The dianion is made up from an Sn(C6H5)2 moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octa-hedral coordination geometry of the Sn(IV) atom. The negative charges are compensated by two surrounding cyclo-hexyl-ammonium cations adopting chair conformations each. In the crystal, anions and cations are linked via a network of N-Hâ¯O hydrogen bonds into a layered arrangement parallel to (101).
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr E Crystallogr Commun
Año:
2015
Tipo del documento:
Article
País de afiliación:
Senegal