Crystal structure of (µ-N,N'-di-benzyl-dithio-oxamidato-κN,S:N',S')bis-[(η(3)-crotyl)palladium(II)].
Acta Crystallogr E Crystallogr Commun
; 71(Pt 2): m40-1, 2015 Feb 01.
Article
en En
| MEDLINE
| ID: mdl-25878846
ABSTRACT
In the centrosymmetric dinuclear title compound, [Pd2(C4H7)2(C16H14N2S2)], the metal atom is η(3)-coordinated by three C atoms of a crotyl ligand [Pd-C = 2.147â
(4), 2.079â
(5) and 2.098â
(5)â
Å], the longest distance influenced by the steric inter-action with the benzyl substituents of the di-benzyl-dithio-oximidate (DTO) ligand. The Pd-N and Pd-S bonds to this ligand are 2.080â
(3) and 2.3148â
(9)â
Å, respectively, completing a square-planar coordination environment for Pd(II). The benzyl groups are oriented so as to maximize the inter-action between a benzylic H atom and an S atom, resulting in a dihedral angle of 77.1â
(2)° between the benzene rings and the metal complex plane. In the crystal, no inter-complex hydrogen-bonding inter-actions are present.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr E Crystallogr Commun
Año:
2015
Tipo del documento:
Article
País de afiliación:
Italia