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Generation, Characterization, and Reactivity of a Cu(II)-Alkylperoxide/Anilino Radical Complex: Insight into the O-O Bond Cleavage Mechanism.
Paria, Sayantan; Ohta, Takehiro; Morimoto, Yuma; Ogura, Takashi; Sugimoto, Hideki; Fujieda, Nobutaka; Goto, Kei; Asano, Kaori; Suzuki, Takeyuki; Itoh, Shinobu.
Afiliación
  • Paria S; Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University , 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.
  • Ohta T; Picobiology Institute, Graduate School of Life Science, University of Hyogo , RSC-UH LP Center, Koto 1-1-1, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan.
  • Morimoto Y; Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University , 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.
  • Ogura T; Picobiology Institute, Graduate School of Life Science, University of Hyogo , RSC-UH LP Center, Koto 1-1-1, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan.
  • Sugimoto H; Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University , 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.
  • Fujieda N; Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University , 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.
  • Goto K; Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology , 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8551, Japan.
  • Asano K; Comprehensive Analysis Center, The Institute of Scientific and Industrial Research (ISIR), Osaka University , 8-1 Mihogaoka, Ibaraki, Osaka 567-0057, Japan.
  • Suzuki T; Comprehensive Analysis Center, The Institute of Scientific and Industrial Research (ISIR), Osaka University , 8-1 Mihogaoka, Ibaraki, Osaka 567-0057, Japan.
  • Itoh S; Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University , 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.
J Am Chem Soc ; 137(34): 10870-3, 2015 Sep 02.
Article en En | MEDLINE | ID: mdl-26291639
ABSTRACT
The reaction of [Cu(I)(TIPT3tren) (CH3CN)]ClO4 (1) and cumene hydroperoxide (C6H5C(CH3)2OOH, ROOH) at -60 °C in CH2Cl2 gave a Cu(II)-alkylperoxide/anilino radical complex 2, the formation of which was confirmed by UV-vis, resonance Raman, EPR, and CSI-mass spectroscopy. The mechanism of formation of 2, as well as its reactivity, has been explored.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Compuestos Organometálicos / Peróxidos / Cobre / Compuestos de Anilina Idioma: En Revista: J Am Chem Soc Año: 2015 Tipo del documento: Article País de afiliación: Japón
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Compuestos Organometálicos / Peróxidos / Cobre / Compuestos de Anilina Idioma: En Revista: J Am Chem Soc Año: 2015 Tipo del documento: Article País de afiliación: Japón