Crystal structure of 2'-[(2',4'-di-fluoro-biphenyl-4-yl)carbon-yl]-1'-phenyl-1',2',5',6',7',7a'-hexa-hydro-spiro-[indole-3,3'-pyrrolizin]-2(1H)-one.
Acta Crystallogr E Crystallogr Commun
; 71(Pt 8): 915-8, 2015 Aug 01.
Article
en En
| MEDLINE
| ID: mdl-26396754
In the title pyrrolizidine derivative, C33H26F2N2O2, both pyrrolidine rings of the pyrrolizidine moiety adopt an envelope conformation. The di-fluoro-phenyl group is oriented at an angle of 54.3â
(1)° with respect to the oxindole moiety. The crystal packing features an N-Hâ¯O hydrogen bond, which forms an R 2 (2)(8) motif, and a C-Hâ¯O inter-action, which generates a C(8) chain along [010]. In addition, this chain structure is stabilized by C-Hâ¯π inter-actions. In one of the pyrrolidine rings, the methyl-ene group forming the flap of an envelope and the H atoms of the adjacent methyl-ene groups are disordered over two sets of sites, with site-occupancy factors of 0.571â
(4) and 0.429â
(4).
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr E Crystallogr Commun
Año:
2015
Tipo del documento:
Article
País de afiliación:
India
Pais de publicación:
Reino Unido