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Crystal structure of 2'-[(2',4'-di-fluoro-biphenyl-4-yl)carbon-yl]-1'-phenyl-1',2',5',6',7',7a'-hexa-hydro-spiro-[indole-3,3'-pyrrolizin]-2(1H)-one.
Fathimunnisa, M; Manikandan, H; Selvanayagam, S; Sridhar, B.
Afiliación
  • Fathimunnisa M; Department of Chemistry, Faculty of Science, Annamalai University, Annamalainagar 608 002, India.
  • Manikandan H; Department of Chemistry, Faculty of Science, Annamalai University, Annamalainagar 608 002, India.
  • Selvanayagam S; Department of Physics, Kings College of Engineering, Punalkulam 613 303, India.
  • Sridhar B; Laboratory of X-ray Crystallography, Indian Institute of Chemical Technology, Hyderabad 500 067, India.
Acta Crystallogr E Crystallogr Commun ; 71(Pt 8): 915-8, 2015 Aug 01.
Article en En | MEDLINE | ID: mdl-26396754
In the title pyrrolizidine derivative, C33H26F2N2O2, both pyrrolidine rings of the pyrrolizidine moiety adopt an envelope conformation. The di-fluoro-phenyl group is oriented at an angle of 54.3 (1)° with respect to the oxindole moiety. The crystal packing features an N-H⋯O hydrogen bond, which forms an R 2 (2)(8) motif, and a C-H⋯O inter-action, which generates a C(8) chain along [010]. In addition, this chain structure is stabilized by C-H⋯π inter-actions. In one of the pyrrolidine rings, the methyl-ene group forming the flap of an envelope and the H atoms of the adjacent methyl-ene groups are disordered over two sets of sites, with site-occupancy factors of 0.571 (4) and 0.429 (4).
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr E Crystallogr Commun Año: 2015 Tipo del documento: Article País de afiliación: India Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr E Crystallogr Commun Año: 2015 Tipo del documento: Article País de afiliación: India Pais de publicación: Reino Unido