Cu(OAc)2-Mediated Reaction of C60 with Ureas for the Preparation of Fulleroimidazolidinones.

Yang, Hai-Tao; Tan, Yi-Chen; Yang, Yang; Sun, Xiao-Qiang; Miao, Chun-Bao

Yang, Hai-Tao; Tan, Yi-Chen; Yang, Yang; Sun, Xiao-Qiang; Miao, Chun-Bao.

Afiliación

Yang HT; Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
Tan YC; Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
Yang Y; Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
Sun XQ; Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
Miao CB; Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.

J Org Chem ; 81(3): 1157-63, 2016 Feb 05.

Article en En | MEDLINE | ID: mdl-26771199

ABSTRACT

ABSTRACT

The Cu(OAc)2-mediated intermolecular diamination reaction of C60 with ureas allows the concise and efficient preparation of fulleroimidazolidinones involving the cleavage of two N-H bonds and formation of two C-N bonds. Both dialkylated and diarylated fulleroimidazolidinones can be synthesized using this method.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2016 Tipo del documento: Article País de afiliación: China