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Ba4Ru3O10.2(OH)1.8: a new member of the layered hexagonal perovskite family crystallised from water.
Hiley, Craig I; Lees, Martin R; Hammond, David L; Kashtiban, Reza J; Sloan, Jeremy; Smith, Ronald I; Walton, Richard I.
Afiliación
  • Hiley CI; Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK. r.i.walton@warwick.ac.uk.
Chem Commun (Camb) ; 52(38): 6375-8, 2016 May 11.
Article en En | MEDLINE | ID: mdl-27074292
ABSTRACT
A new barium ruthenium oxyhydroxide Ba4Ru3O10.2(OH)1.8 crystallises under hydrothermal conditions at 200 °C powder neutron diffraction data show it adopts an 8H hexagonal perovskite structure with a new stacking sequence, while high resolution electron microscopy reveals regions of ordered layers of vacant Ru sites, and magnetometry shows antiferromagnetism with TN = 200(5) K.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: Reino Unido