Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex.

Petersen, Allan R; White, Andrew J P; Britovsek, George J P

Petersen, Allan R; White, Andrew J P; Britovsek, George J P.

Afiliación

Petersen AR; Department of Chemistry, Imperial College London, Exhibition Road, London, SW7 2AZ, UK. g.britovsek@imperial.ac.uk.

Dalton Trans ; 45(37): 14520-3, 2016 Oct 07.

Article en En | MEDLINE | ID: mdl-27283971

ABSTRACT

ABSTRACT

The 6,6''-diaminoterpyridine palladium(ii) methylperoxo complex eliminates methyl hydroperoxide and reacts with acetone to form a novel hemi-aminal palladium complex, whereas the analogous platinum(ii) complex generates formaldehyde and a platinum(ii) hydroxo complex.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: Reino Unido

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