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Anomalous but massive removal of two organic dye pollutants simultaneously.
Meng, Zilin; Zhang, Yihe; Zhang, Zhilei; Zhang, Qian; Chu, Paul K; Komarneni, Sridhar; Lv, Fengzhu.
Afiliación
  • Meng Z; Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China; Department of Ecosystem Science and Management, Materials Research I
  • Zhang Y; Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China. Electronic address: zyh@cugb.edu.cn.
  • Zhang Z; Drilling Research Institute, CNPC, Beijing, China.
  • Zhang Q; Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China.
  • Chu PK; Department of Physics & Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China.
  • Komarneni S; Department of Ecosystem Science and Management, Materials Research Institute, Materials Research Laboratory, the Pennsylvania State University, University Park, PA 16802, United States. Electronic address: Komarneni@psu.edu.
  • Lv F; Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China. Electronic address: lfz619@cugb.edu.cn.
J Hazard Mater ; 318: 54-60, 2016 Nov 15.
Article en En | MEDLINE | ID: mdl-27399147
A one-pot method to remove two organic dye contaminants and alkali simultaneously from alkaline wastewater was developed by forming Zn-Al layered double hydroxide (ZnAl-LDH). Using this process, not only alkali but also methyl orange (MO), an anionic contaminant was totally removed from wastewater. In addition, cationic contaminant, methylene blue (MB) was also removed effectively while maintaining the high removal efficiency of MO. The removal efficiency of MO was almost 100% and the pH of the treated wastewater decreased from 12 to 7.38. The charge-limited removal process, molecular arrangement of the contaminants in LDHs, and the anomalous removal mechanism were analyzed experimentally and through simulation. After MO accumulated in the interlayers of LDH by electrostatic interaction, MB entered and trapped by hydrophobic interaction.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Hazard Mater Asunto de la revista: SAUDE AMBIENTAL Año: 2016 Tipo del documento: Article Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Hazard Mater Asunto de la revista: SAUDE AMBIENTAL Año: 2016 Tipo del documento: Article Pais de publicación: Países Bajos