A study on the reaction of 16-dehydropregnenolone acetate with 2-aminobenzimidazole.
Steroids
; 117: 71-76, 2017 01.
Article
en En
| MEDLINE
| ID: mdl-27644145
ABSTRACT
The condensation of 16-dehydropregnenolone acetate with 2-aminobenzimidazole was studied. The polycyclic aromatic product was formed as a single regioisomer in a cascade reaction comprising addition, cyclization, autoxidation, and aromatization, in addition to the rearranged D-homo product. The reaction mechanism based on DFT calculations is proposed.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Pregnenolona
/
Bencimidazoles
Idioma:
En
Revista:
Steroids
Año:
2017
Tipo del documento:
Article