Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation.

Dorel, Ruth; de Mendoza, Paula; Calleja, Pilar; Pascual, Sergio; González-Cantalapiedra, Esther; Cabello, Noemí; Echavarren, Antonio M

Dorel, Ruth; de Mendoza, Paula; Calleja, Pilar; Pascual, Sergio; González-Cantalapiedra, Esther; Cabello, Noemí; Echavarren, Antonio M.

Afiliación

Dorel R; Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
de Mendoza P; Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
Calleja P; Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
Pascual S; Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
González-Cantalapiedra E; Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
Cabello N; Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
Echavarren AM; Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain; Departament de Química Orgànica i Analítica Universitat Rovira i Virgili C/ Marcel·lí Domingo s/n 43007 Tarragona Spain.

European J Org Chem ; 2016(19): 3171-3176, 2016 07.

Article en En | MEDLINE | ID: mdl-27774038

ABSTRACT

ABSTRACT

The synthesis of a new C3v -symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium-catalyzed intramolecular arylation of a syn-trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C60, as detected by LDI-MS.

Palabras clave

Arylation; Fullerenes; Mass spectrometry; Palladium; Truxene

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: European J Org Chem Año: 2016 Tipo del documento: Article