Crystal structure of hexa-kis-(dimethyl sulfoxide-κO)manganese(II) tetra-iodide.
Acta Crystallogr E Crystallogr Commun
; 72(Pt 12): 1791-1793, 2016 Dec 01.
Article
en En
| MEDLINE
| ID: mdl-27980832
ABSTRACT
The title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I42- tetra-iodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octa-hedrally coordinated by O atoms of the DMSO mol-ecule with an Mn-O distance of 2.1808â
(12)â
Å. The I42- anion contains a neutral I2 mol-ecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetra-iodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.
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MEDLINE
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En
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Acta Crystallogr E Crystallogr Commun
Año:
2016
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Article