A Mixed-Cluster Approach for Building a Highly Porous Cobalt(II) Isonicotinic Acid Framework: Gas Sorption Properties and Computational Analyses.

Chen, Di-Ming; Zhang, Nan-Nan; Liu, Chun-Sen; Jiang, Zhi-Hao; Wang, Xing-Dong; Du, Miao

Chen, Di-Ming; Zhang, Nan-Nan; Liu, Chun-Sen; Jiang, Zhi-Hao; Wang, Xing-Dong; Du, Miao.

Afiliación

Chen DM; Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry , Zhengzhou 450002, P. R. China.
Zhang NN; Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry , Zhengzhou 450002, P. R. China.
Liu CS; Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry , Zhengzhou 450002, P. R. China.
Jiang ZH; Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry , Zhengzhou 450002, P. R. China.
Wang XD; Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry , Zhengzhou 450002, P. R. China.
Du M; Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry , Zhengzhou 450002, P. R. China.

Inorg Chem ; 56(5): 2379-2382, 2017 Mar 06.

Article en En | MEDLINE | ID: mdl-28217998

ABSTRACT

ABSTRACT

A unique channel-type metal-organic framework (MOF) built up from mixed square-planar Co4(µ2-OH)4(µ4-OH) and cuboidal Co4(µ3-OH)4 clusters with an isonicotinic acid ligand has been successfully fabricated that demonstrates the highest specific surface area and high H2 uptake capacities among all of the cobalt(II) isonicotinic acid frameworks reported so far.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2017 Tipo del documento: Article