Partial Reduction and Selective Transfer of Hydrogen Chloride on Catalytic Gold Nanoparticles.
Angew Chem Int Ed Engl
; 56(23): 6435-6439, 2017 06 01.
Article
en En
| MEDLINE
| ID: mdl-28452171
ABSTRACT
HCl in solution accepts electron density from Auâ
NPs and partially reduces at room temperature, as occurs with other simple diatomic molecules, such as O2 and H2 . The activation can be run catalytically in the presence of alkynes to give exclusively E-vinyl chlorides, after the regio- and stereoselective transfer of HCl. Based also on this method, vinyl chloride monomer (VCM) can be produced in a milder and greener way than current industrial processes.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2017
Tipo del documento:
Article
País de afiliación:
España