Molecular tectonics: gas adsorption and chiral uptake of (l)- and (d)-tryptophan by homochiral porous coordination polymers.
Chem Commun (Camb)
; 53(42): 5740-5743, 2017 May 23.
Article
en En
| MEDLINE
| ID: mdl-28492631
ABSTRACT
Combinations of two enantiomerically pure organic tectons 1 and 3 with either Zn(ii) or Cu(ii) cations lead to the formation of four homochiral 3D networks among which two, 1-Cu and 3-Cu, are robust porous crystals displaying homochiral cavities and permanent microporosity. 3-Cu porous crystals capture 66% and 20% of l- and d-tryptophan, respectively, after 30 min of adsorption.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2017
Tipo del documento:
Article