Multiple Metal-Metal Bond or No Bond? The Electronic Structure of V2 O2.
Angew Chem Int Ed Engl
; 56(40): 12340-12343, 2017 09 25.
Article
en En
| MEDLINE
| ID: mdl-28759144
ABSTRACT
Detailed knowledge of the electronic structure of vanadium oxide clusters provides the basis for understanding and tuning their significant catalytic properties. However, already for the simple four-atom V2 O2 molecule, there are contradictory reports in the literature regarding the electronic ground state and a possible vanadium-vanadium bond. We herein show through a combination of experimental (matrix isolation) studies and theoretical results that there is a multiple vanadium-vanadium bond in this benchmark vanadium oxide molecule.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2017
Tipo del documento:
Article
País de afiliación:
Alemania