Phosphinoyl Radical-Initiated &#945;,ß-Aminophosphinoylation of Alkenes.

Li, Jian-An; Zhang, Pei-Zhi; Liu, Kui; Shoberu, Adedamola; Zou, Jian-Ping; Zhang, Wei

Phosphinoyl Radical-Initiated α,ß-Aminophosphinoylation of Alkenes.

Li, Jian-An; Zhang, Pei-Zhi; Liu, Kui; Shoberu, Adedamola; Zou, Jian-Ping; Zhang, Wei.

Afiliación

Li JA; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University , Jiangsu 215123, China.
Zhang PZ; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University , Jiangsu 215123, China.
Liu K; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University , Jiangsu 215123, China.
Shoberu A; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University , Jiangsu 215123, China.
Zou JP; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University , Jiangsu 215123, China.
Zhang W; Department of Chemistry, University of Massachusetts Boston, Massachusetts 02125, United States.

Org Lett ; 19(17): 4704-4706, 2017 09 01.

Article en En | MEDLINE | ID: mdl-28832163

ABSTRACT

ABSTRACT

A new double functionalization reaction of alkenes through AgNO3-mediated phosphinoyl radical addition followed by Cu(II)-catalyzed amination is introduced. This one-pot, three-component reaction is performed under mild conditions to afford α,ß-aminophosphinoylation products.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2017 Tipo del documento: Article País de afiliación: China

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