Reaction Electronic Flux Perspective on the Mechanism of the Zimmerman Di-π-methane Rearrangement.
J Org Chem
; 83(11): 5969-5974, 2018 06 01.
Article
en En
| MEDLINE
| ID: mdl-29486121
ABSTRACT
The reaction electronic flux (REF) offers a powerful tool in the analysis of reaction mechanisms. Noteworthy, the relationship between aromaticity and REF can eventually reveal subtle electronic events associated with reactivity in aromatic systems. In this work, this relationship was studied for the triplet Zimmerman di-π-methane rearrangement. The aromaticity loss and gain taking place during the reaction is well acquainted by the REF, thus shedding light on the electronic nature of reactions involving dibenzobarrelenes.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Org Chem
Año:
2018
Tipo del documento:
Article
País de afiliación:
Chile