Abnormal sergeants-and-soldiers effects of poly(quinoxaline-2,3-diyl)s enabling discrimination of one-carbon homologous n-alkanes through a highly sensitive solvent-dependent helix inversion.
Chem Commun (Camb)
; 54(50): 6867-6870, 2018 Jun 19.
Article
en En
| MEDLINE
| ID: mdl-29761800
ABSTRACT
Poly(quinoxaline-2,3-diyl)s bearing (S)-3-octyloxymethyl and n-propoxymethyl side chains show an abnormal sergeants-and-soldiers effect in n-alkane solvents, which allows the development of a series of PQXs that exhibit an extremely sensitive solvent-dependent helix inversion that permits the discrimination of n-alkane solvents that differ by a single methylene group (e.g. n-heptane and n-octane).
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Tipo de estudio:
Diagnostic_studies
/
Prognostic_studies
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2018
Tipo del documento:
Article