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Mixed X-Site Formate-Hypophosphite Hybrid Perovskites.
Wu, Yue; Halat, David M; Wei, Fengxia; Binford, Trevor; Seymour, Ieuan D; Gaultois, Michael W; Shaker, Sammy; Wang, John; Grey, Clare P; Cheetham, Anthony K.
Afiliación
  • Wu Y; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK.
  • Halat DM; Department of Materials Science and Engineering, National University of Singapore, Singapore, 117574, Singapore.
  • Wei F; Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, UK.
  • Binford T; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK.
  • Seymour ID; Institute of Materials Research and Wngineering, A*STAR, 2 Fusionopolis way, Innovis, Singapore, 138634, Singapore.
  • Gaultois MW; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK.
  • Shaker S; Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, UK.
  • Wang J; Leverhulme Research Centre for Functional Materials Design, The Materials Innovation Factory, Department of Chemistry, University of Liverpool, Liverpool, L7 3NY, UK.
  • Grey CP; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK.
  • Cheetham AK; Current address: David Geffen School of Medicine, University of California, 10833 Le Conte Ave, Los Angeles, CA, 90095, USA.
Chemistry ; 24(44): 11309-11313, 2018 Aug 06.
Article en En | MEDLINE | ID: mdl-29920832
Following the recent discovery of a new family of hybrid ABX3 perovskites where X=(H2 POO)- (hypophosphite), this work reports a facile synthesis for mixed X-site formate perovskites of composition [GUA]Mn(HCOO)3-x (H2 POO)x , with two crystallographically distinct, partially ordered intermediate phases with x=0.84 and 1.53, corresponding to ca. 30 and 50 mol % hypophosphite, respectively. These phases are characterised by single-crystal XRD and solid-state NMR spectroscopy, and their magnetic properties are reported.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Óxidos / Ácidos Fosfínicos / Titanio / Compuestos de Manganeso / Compuestos de Calcio / Formiatos Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article Pais de publicación: Alemania
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Óxidos / Ácidos Fosfínicos / Titanio / Compuestos de Manganeso / Compuestos de Calcio / Formiatos Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article Pais de publicación: Alemania