Gold(I)-Catalyzed Tandem Cycloisomerization of 1,5-Enyne Ethers by Hydride Transfer.
Angew Chem Int Ed Engl
; 57(35): 11365-11368, 2018 Aug 27.
Article
en En
| MEDLINE
| ID: mdl-29989283
ABSTRACT
A novel gold-catalyzed tandem protocol, initiated by hydride transfer in the presence of catalytic (C6 F5 )3 PAuCl/AgSbF6 , for the formation of fused polycyclic ring systems has been achieved. This tandem reaction provides rapid access to various fused polycyclic species in a single chemical operation, leading to stereospecific formation of two carbon-carbon bonds and three rings.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2018
Tipo del documento:
Article
País de afiliación:
China