The steam gasification reactivity and kinetics of municipal solid waste chars derived from rapid pyrolysis.
Waste Manag
; 80: 64-72, 2018 Oct.
Article
en En
| MEDLINE
| ID: mdl-30455028
ABSTRACT
Municipal solid waste treatment has been and will continue to be a major issue facing countries worldwide, and gasification has recently gained more attention as an efficient and clean technology. The steam gasification characteristics and kinetics of five different municipal solid waste chars had been investigated by the method of isothermal thermogravimetric analysis. The results showed that the gasification reactivity increased with gasification temperature. Effect of H/C and O/C ratios, ash composition and particle pore structure of chars on gasification reactivity were studied, which illustrated that the H/C and O/C ratios and ash composition had great influence on gasification reactivity and the pore structure cannot explain well in this study. A homogeneous model, unreacted shrinking core model and random pore model were employed to describe the kinetic behavior of different chars, and the kinetic parameters were also obtained. Finally, through the evaluation of the three kinetic models by comparing the experimental data with the fitted results, the random pore model was determined to perform best. This study should, therefore, be of some value to solid waste gasification industrialization.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Vapor
/
Residuos Sólidos
Tipo de estudio:
Prognostic_studies
Idioma:
En
Revista:
Waste Manag
Asunto de la revista:
SAUDE AMBIENTAL
/
TOXICOLOGIA
Año:
2018
Tipo del documento:
Article
País de afiliación:
China