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Raman spectra study hydrogen bonds network in ice Ih with cooling.
Wang, Ying; Li, Fabing; Li, Zhanlong; Sun, Chenglin; Wang, Shenghan; Men, Zhiwei.
Afiliación
  • Wang Y; Coherent Light and Atomic and Molecular Spectroscopy Laboratory, College of Physics, Jilin University, Changchun 130012, China.
  • Li F; Coherent Light and Atomic and Molecular Spectroscopy Laboratory, College of Physics, Jilin University, Changchun 130012, China.
  • Li Z; Coherent Light and Atomic and Molecular Spectroscopy Laboratory, College of Physics, Jilin University, Changchun 130012, China.
  • Sun C; Key Laboratory of Physics and Technology for Advanced Batteries, College of Physics, Jilin University, Changchun 130012, China.
  • Wang S; Coherent Light and Atomic and Molecular Spectroscopy Laboratory, College of Physics, Jilin University, Changchun 130012, China; Key Laboratory of Physics and Technology for Advanced Batteries, College of Physics, Jilin University, Changchun 130012, China. Electronic address: shenghan@jlu.edu.cn.
  • Men Z; Coherent Light and Atomic and Molecular Spectroscopy Laboratory, College of Physics, Jilin University, Changchun 130012, China. Electronic address: zwmen@jlu.edu.cn.
Spectrochim Acta A Mol Biomol Spectrosc ; 220: 117131, 2019 Sep 05.
Article en En | MEDLINE | ID: mdl-31158605
ABSTRACT
The Raman spectra of ice Ih (H2O and HDO) in the temperatures range from 253 to 83 K are measured. The results show that Raman peaks shift to low- or high-wavenumber due to the influence of temperature on hydrogen bonds dynamics. Importantly, Raman shifts are linear relationship with temperatures and its slope fully reflects the change of hydrogen bonds length. Finally, Raman intensity of ice Ih dependent on temperatures are also discussed.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Spectrochim Acta A Mol Biomol Spectrosc Asunto de la revista: BIOLOGIA MOLECULAR Año: 2019 Tipo del documento: Article País de afiliación: China
Texto completo
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Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Spectrochim Acta A Mol Biomol Spectrosc Asunto de la revista: BIOLOGIA MOLECULAR Año: 2019 Tipo del documento: Article País de afiliación: China