An often-overestimated adverse effect of halides in heat/persulfate-based degradation of wastewater contaminants.
Environ Int
; 130: 104918, 2019 09.
Article
en En
| MEDLINE
| ID: mdl-31234000
ABSTRACT
Halides (X-) in the industrial wastewater are usually thought to adversely affect the degradation kinetics and mineralization rates in several SO4--based advanced oxidation processes. However, their unfavorable effects might be overestimated, particularly the heat/persulfate (PS) system as tested in the present study. Here the degradation of phenol, benzoic acid, coumarin and acid orange 7 (AO7) was examined with the presence of chloride or bromide in a heat/PS process. Cl- was found to have a dual effect (inhibition followed by enhancement) on the decomposition rates of organic pollutants, whereas the effects of Br- are insignificant within the tested concentration (0-0.2â¯mM). However, some chlorinated or brominated compounds were still identified in this heat/PS system. Unexpectedly, the mineralization rates of AO7, phenol, benzoic acid and coumarin were not apparently inhibited. In addition, the formation of adsorbable organic halogen (AOX) in the heat/PS system was much less than those in the peroxymonosulfate (PMS)/Cl- or PMS/Br- systems. According to the results of kinetic modeling, SO4- was the dominating radical for AO7 degradation without Cl- or Br-, but Cl2- was the main oxidant in the presence of Cl-, SO4-, Br and Br2- were responsible for the oxidation of AO7 in the presence of Br-. The present study assumes that X2/HOX, rather than halogen radicals, is responsible for the enhanced formation of organohalogens. These findings are meaningful to evaluate the PS-based technologies for the high-salinity wastewater and to develop useful strategies for mitigating the negative effects of halides in advanced oxidation processes (AOPs).
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Contaminantes Químicos del Agua
/
Bromuros
/
Cloruros
/
Eliminación de Residuos Líquidos
/
Aguas Residuales
Tipo de estudio:
Prognostic_studies
Idioma:
En
Revista:
Environ Int
Año:
2019
Tipo del documento:
Article
País de afiliación:
China