Surfactant-Type Catalyst for Aerobic Oxidative Coupling of Hydrazine with Thiol in Water.

Ren, Xuanhe; Tang, Shanyu; Li, Longjia; Li, Jiao; Liang, Helong; Li, Ganzhong; Yang, Guanyu; Li, Heng; Yuan, Bingxin

Ren, Xuanhe; Tang, Shanyu; Li, Longjia; Li, Jiao; Liang, Helong; Li, Ganzhong; Yang, Guanyu; Li, Heng; Yuan, Bingxin.

Afiliación

Ren X; College of Chemistry and Molecular Engineering , Zhengzhou University , Henan 450001 , China.
Tang S; College of Chemistry and Molecular Engineering , Zhengzhou University , Henan 450001 , China.
Li L; College of Chemistry and Molecular Engineering , Zhengzhou University , Henan 450001 , China.
Li J; College of Chemistry and Molecular Engineering , Zhengzhou University , Henan 450001 , China.
Liang H; College of Chemistry and Molecular Engineering , Zhengzhou University , Henan 450001 , China.
Li G; College of Chemistry and Molecular Engineering , Zhengzhou University , Henan 450001 , China.
Yang G; College of Chemistry and Molecular Engineering , Zhengzhou University , Henan 450001 , China.
Li H; College of Chemistry and Molecular Engineering , Zhengzhou University , Henan 450001 , China.
Yuan B; College of Chemistry and Molecular Engineering , Zhengzhou University , Henan 450001 , China.

J Org Chem ; 84(13): 8683-8690, 2019 07 05.

Article en En | MEDLINE | ID: mdl-31244150

ABSTRACT

ABSTRACT

A series of PEG-functionalized nitrogen ligands were developed to conduct an aerobic oxidative cross-coupling reaction between alkyl- or aryl-hydrazines with thiols in water. This surfactant-type catalyst enables high efficiencies and selectivities, while tolerating a large variety of functional groups. The mother liquor is still catalytically active after five runs.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2019 Tipo del documento: Article País de afiliación: China