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The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis.
Pichon, Delphine; Soleilhavoup, Michele; Morvan, Jennifer; Junor, Glen P; Vives, Thomas; Crévisy, Christophe; Lavallo, Vincent; Campagne, Jean-Marc; Mauduit, Marc; Jazzar, Rodolphe; Bertrand, Guy.
Afiliación
  • Pichon D; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Soleilhavoup M; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
  • Morvan J; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Junor GP; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
  • Vives T; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Crévisy C; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Lavallo V; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
  • Campagne JM; Institut Charles Gerhardt , UMR 5253 CNRS-UM2-UM1-ENSCM , 8 Rue l'Ecole Normale , 34296 Montpellier , France.
  • Mauduit M; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Jazzar R; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
  • Bertrand G; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
Chem Sci ; 10(33): 7807-7811, 2019 Sep 07.
Article en En | MEDLINE | ID: mdl-31588330
The popularity of NHCs in transition metal catalysis has prompted the development of chiral versions as electron-rich neutral stereodirecting ancillary ligands for enantioselective transformations. Herein we demonstrate that cyclic (alkyl)(amino)carbene (CAAC) ligands can also engage in asymmetric transformations, thereby expanding the toolbox of available chiral carbenes.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Sci Año: 2019 Tipo del documento: Article Pais de publicación: Reino Unido
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Sci Año: 2019 Tipo del documento: Article Pais de publicación: Reino Unido