Fused-pentagon C70Cl26 obtained via chlorination-promoted Stone-Wales cage transformations of C70.

Brotsman, Victor A; Kemnitz, Erhard; Troyanov, Sergey I

Fused-pentagon C₇₀Cl₂₆ obtained via chlorination-promoted Stone-Wales cage transformations of C₇₀.

Brotsman, Victor A; Kemnitz, Erhard; Troyanov, Sergey I.

Afiliación

Brotsman VA; Chemistry Department, Moscow State University, Leninskie Gory, 119991 Moscow, Russia. stroyano@thermo.chem.msu.ru.
Kemnitz E; Institute of Chemistry, Humboldt University of Berlin, Brook-Taylor-Str. 2, 12489, Berlin, Germany.
Troyanov SI; Chemistry Department, Moscow State University, Leninskie Gory, 119991 Moscow, Russia. stroyano@thermo.chem.msu.ru.

Chem Commun (Camb) ; 55(89): 13378-13381, 2019 Nov 18.

Article en En | MEDLINE | ID: mdl-31633714

RESUMEN

High-temperature (360 °C) chlorination of C70 with VCl4 or SbCl5 yields only IPR C70Cl26/28. Chlorination with SbCl5 at 440 °C resulted in a skeletal transformation via a two-step Stone-Wales rearrangement and the formation of non-IPR 8005C70Cl26 with two fused pentagon pairs in the carbon cage which was established by single crystal X-ray diffraction.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article País de afiliación: Rusia Pais de publicación: Reino Unido

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