Carbon Nanomembranes from Aromatic Carboxylate Precursors.
Chemphyschem
; 21(10): 1006-1011, 2020 05 18.
Article
en En
| MEDLINE
| ID: mdl-32202365
ABSTRACT
Self-assembled monolayers (SAMs) serve as convenient platform for fabricating carbon nanomembranes (CNMs) of extended lateral dimensions. Highly porous CNMs are emerging as interesting materials for membrane technologies as they exhibit selectivity for water permeation and, owing to their reduced dimensionality, promise increased energy efficiency compared to established systems. In the present study terphenylcarboxylate SAMs, prepared on silver underpotential deposited on Au and irradiated by 100â
eV electrons, were successfully converted into free-standing CNMs. Infrared and X-ray photoelectron spectroscopy reveal pronounced chemical changes both of the anchoring carboxylate moiety and the aromatic backbone upon electron irradiation. Permeation studies showed high specificity for water as demonstrated by the separation from tetrahydrofuran. Compared to thiols on gold, the standard CNM precursor system, the carboxylic acid based SAM exhibits equivalent characteristics. This suggests that electron-induced carbonization is insensitive to the particular choice of the anchor moiety and, therefore, the choice of precursor molecules can be extended to the versatile class of aromatic carboxylic acids.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chemphyschem
Asunto de la revista:
BIOFISICA
/
QUIMICA
Año:
2020
Tipo del documento:
Article
País de afiliación:
Alemania