Enhanced catalytic activity of copper complexes in microgels for aerobic oxidation of benzyl alcohols.
Chem Commun (Camb)
; 56(42): 5601-5604, 2020 May 27.
Article
en En
| MEDLINE
| ID: mdl-32355940
ABSTRACT
Catalytically active copper bis(pyrazolyl)methane complexes have been anchored into pVCL-GMA microgels on specified positions within the microgel network. Functionalized microgels act as nanoreactors providing a tailored environment and stabilization for the copper complexes thus increasing the product yield. The oxidation of benzyl alcohols to their respective aldehydes was chosen as a test reaction to show the enhancement of catalytic activity due to the immobilization of the copper complex compared to the copper salt and the molecular copper complex.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2020
Tipo del documento:
Article
País de afiliación:
Alemania