Highly-efficient, Rapid and continuous separation of surfactant-stabilized Oil/Water emulsions by selective under-liquid adhering emulsified droplets.
J Hazard Mater
; 400: 123132, 2020 Dec 05.
Article
en En
| MEDLINE
| ID: mdl-32563901
ABSTRACT
Anti-adhesion is considered to be the basis for oil/water separation. However, this principle may not the superior choice for surfactant-stabilized oil/water emulsions owing to the inevitable adhesion of surfactant on the membrane, resulting in further adhesion of emulsified droplets and therefore attenuation in separation performance. Herein, we demonstrated a novel separation strategy for surfactant-stabilized oil/water emulsions by exploiting rather than preventing adhesion. A modified filter paper (mFP) with strong under-liquid adhesion to emulsified droplets was prepared, endowing it excellent separation performance for both surfactant-stabilized and surfactant free emulsions with very high separation efficiency (up to 99.9 %). Furthermore, the Random layer stacked scraps of mFP (RLS-mFP) were used to construct the separation device, which provided a labyrinthine but unobstructed flow path for emulsion because of the randomly stacked form and relatively large interspace among mFP scraps. The RLS-mFP has excellent separation performance with the separation flux for surfactant-stabilized oil-in-water and water-in-oil emulsions achieving 1035 and 3570 L m-2 h-1 respectively only under gravity. After 1-hour continuous separation, both flux and separation efficiency of RLS-mFP showed almost no decline comparing to initial flux for surfactant-stabilized emulsions. Meanwhile, the mFP could be easily recycled by rinsing and reused at least 50 times without sacrificing separation performance.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Hazard Mater
Asunto de la revista:
SAUDE AMBIENTAL
Año:
2020
Tipo del documento:
Article
País de afiliación:
China