Comparative Investigation of Corrosion-Mitigating Behavior of Thiadiazole-Derived Bis-Schiff Bases for Mild Steel in Acid Medium: Experimental, Theoretical, and Surface Study.

ABSTRACT

In the present study, comparative analyses of corrosion inhibition property of few thiadiazole-derived bis-Schiff bases for mild steel in 1 M HCl were done. Various electrochemical experiments (electrochemical impedance spectroscopy and potentiodynamic polarization), as well as weight loss experiments, were employed to study the anticorrosion activity of bis-Schiff bases as inhibitors. The highest inhibition efficiency was obtained at an optimum concentration of 125 ppm for all inhibitors. Potentiodynamic polarization studies explain the mixed type but predominantly the cathodic nature of all inhibitors. The Langmuir adsorption isotherm was used to describe the mechanism of adsorption. The change in the value of activation energy on the addition of inhibitors reflects the mixed mode of interaction between the inhibitor and metallic surface. Scanning electron microscopy with energy-dispersive spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy analyses confirmed the adsorption of bis-Schiff bases on the metal surface and thereby shielding from corrosion. Besides, the relevance between inhibition efficiency and the molecular structure of an inhibitor was theoretically examined via quantum chemical calculations and molecular dynamics simulations. All the results show consistent agreement with each other.