Oxygen Doping in Graphitic Carbon Nitride for Enhanced Photocatalytic Hydrogen Evolution.
ChemSusChem
; 13(18): 5041-5049, 2020 Sep 18.
Article
en En
| MEDLINE
| ID: mdl-32662925
ABSTRACT
The incorporation of oxygenic groups could remarkably enhance the light absorption and charge separation of graphitic carbon nitride (g-C3 N4 ). The intrinsic role of oxygenic species on photocatalytic activity in g-C3 N4 has been intensively studied, but it is still not fully explored. Herein, the essential relationships between oxygenic functionalities and the catalytic performance are revealed. Results demonstrate that C-O-C functionality as an electron trap could help to increase the resistance of conduction transfer (Rct ) by limiting electrons transfer in CNx. In contrast, N-C-O functionality between different tri-s-triazine unites could promote the electrons transfer, leading to a reduced Rct in CNx. The best H2 production rate (3.70â
mmol h-1 g-1 , 12.76-fold higher than that of CN) is obtained over CN3, because of the highest N-C-O ratio (rN-C-O ). The apparent quantum efficiency (AQE) of CN3 at 405â
nm, 420â
nm, 450â
nm, 500â
nm and 550â
nm is 33.90 %, 20.88 %, 8.25 %, 3.66 % and 1.01 %, respectively.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
ChemSusChem
Asunto de la revista:
QUIMICA
/
TOXICOLOGIA
Año:
2020
Tipo del documento:
Article