Construction and Regulation of a Surface Protophilic Environment to Enhance Oxygen Reduction Reaction Electrocatalytic Activity.
ACS Appl Mater Interfaces
; 12(37): 41269-41276, 2020 Sep 16.
Article
en En
| MEDLINE
| ID: mdl-32805853
ABSTRACT
Pyrolytic transition metal nitrogen-carbon (M-N/C) materials are considered as the most promising alternatives for platinum-based catalysts toward oxygen reduction reaction (ORR). As the proton-coupled electron transfer step in ORR has been proven to be a rate-determining step in the M-N/C catalysts, we envisaged that building a protophilic surface might be helpful to enhance the ORR activity. Herein, a polyaniline decoration strategy was put forward and realized to confer the Fe-N/C catalyst with a surface protophilic environment. A 20 mV positive shift in half-wave potential was observed owing to the enriched interfacial proton concentration, corresponding to a tripled turnover frequency under acidic conditions (from 0.46 to 1.28 e·s-1·sites-1). Our work blazed a new path toward the design of M-N/C ORR catalysts, commencing via the ORR kinetics.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
ACS Appl Mater Interfaces
Asunto de la revista:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Año:
2020
Tipo del documento:
Article
País de afiliación:
China