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Geometry-Directed Self-Assembly of Polymeric Molecular Frameworks.
Yan, Xiao-Yun; Guo, Qing-Yun; Lin, Zhiwei; Liu, Xian-You; Yuan, Jun; Wang, Jing; Wang, Haomin; Liu, Yuchu; Su, Zebin; Liu, Tong; Huang, Jiahao; Zhang, Ruimeng; Wang, Yicong; Huang, Mingjun; Zhang, Wei; Cheng, Stephen Z D.
Afiliación
  • Yan XY; South China Advanced Institute for Soft Matter Science and Technology, School of Molecular Science and Engineering, South China University of Technology, Guangzhou, 510640, China.
  • Guo QY; Department of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH, 44325-3909, USA.
  • Lin Z; South China Advanced Institute for Soft Matter Science and Technology, School of Molecular Science and Engineering, South China University of Technology, Guangzhou, 510640, China.
  • Liu XY; Department of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH, 44325-3909, USA.
  • Yuan J; Department of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH, 44325-3909, USA.
  • Wang J; South China Advanced Institute for Soft Matter Science and Technology, School of Molecular Science and Engineering, South China University of Technology, Guangzhou, 510640, China.
  • Wang H; South China Advanced Institute for Soft Matter Science and Technology, School of Molecular Science and Engineering, South China University of Technology, Guangzhou, 510640, China.
  • Liu Y; South China Advanced Institute for Soft Matter Science and Technology, School of Molecular Science and Engineering, South China University of Technology, Guangzhou, 510640, China.
  • Su Z; Department of Chemistry, Lehigh University, 6 E Packer Avenue, Bethlehem, PA, 18015, USA.
  • Liu T; Department of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH, 44325-3909, USA.
  • Huang J; Department of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH, 44325-3909, USA.
  • Zhang R; Department of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH, 44325-3909, USA.
  • Wang Y; Department of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH, 44325-3909, USA.
  • Huang M; Department of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH, 44325-3909, USA.
  • Zhang W; South China Advanced Institute for Soft Matter Science and Technology, School of Molecular Science and Engineering, South China University of Technology, Guangzhou, 510640, China.
  • Cheng SZD; South China Advanced Institute for Soft Matter Science and Technology, School of Molecular Science and Engineering, South China University of Technology, Guangzhou, 510640, China.
Angew Chem Int Ed Engl ; 60(4): 2024-2029, 2021 Jan 25.
Article en En | MEDLINE | ID: mdl-33111472
Despite the significant advances in creating assembled structures from polymers, engineering the assembly of polymeric materials into framework structures remains an outstanding challenge. In this work, we present a facile strategy to construct polymeric molecular frameworks through the assembly of T-shape polymer-rod-sphere amphiphiles in the bulk state. Various frameworks are yielded as a result of delicate interplays among three components of the T-shape amphiphiles. The internal structure of frameworks was revealed by combining experimental investigations and computational simulations. The frameworks display good solution-processability, thermal stability, and uniform pore-forming capability, which endow the resultant frameworks with great potential in scalable fabrications.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2021 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2021 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania