Carbamoyl Fluoride-Enabled Enantioselective Ni-Catalyzed Carbocarbamoylation of Unactivated Alkenes.

Li, Yue; Zhang, Feng-Ping; Wang, Rong-Hua; Qi, Shao-Long; Luan, Yu-Xin; Ye, Mengchun

Li, Yue; Zhang, Feng-Ping; Wang, Rong-Hua; Qi, Shao-Long; Luan, Yu-Xin; Ye, Mengchun.

Afiliación

Li Y; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
Zhang FP; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
Wang RH; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
Qi SL; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
Luan YX; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
Ye M; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.

J Am Chem Soc ; 142(47): 19844-19849, 2020 11 25.

Article en En | MEDLINE | ID: mdl-33170685

ABSTRACT

ABSTRACT

A carbamoyl fluoride-enabled enantioselective Ni-catalyzed carbocarbamoylation of unactivated alkenes was developed, providing a broad range of chiral Î³-lactams bearing an all-carbon quaternary center in 45-96% yield and 38-97% ee.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2020 Tipo del documento: Article País de afiliación: China

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