Porous nanotube networks of SnO2/MoO3@Graphene as anodes for rechargeable lithium-ion batteries.

ABSTRACT

We successfully fabricated composite porous nanotube networks of SnO2/MoO3@Graphene through electrospinning and used it as lithium-ion battery anodes. When the ratio of SnO2 to MoO3 is 11, the composite of SnO2/MoO3 delivers a high capacity of 560 mAh g-1 at 1 A g-1 after 300 cycles. The excellent electrochemical performance was attributed to the unique 3D porous nanotube network structure which could provide more transmission channels for Li+ ions and electrons, and provide more electrochemical reaction sites. The hybrid nanostructure can also weaken local stress and relieve volume expansion which contributes to the attractive cycling stability. Moreover, we added a small amount of graphene in the composite to improve the electrical conductivity, and the SnO2/MoO3@Graphene composite showed favorable electrochemical performance (798 mAh g-1 at 1 A g-1 after 300 cycles). Finally, electrospinning technology is a simple and efficient synthesis strategy, which can promote the preparation of different types of metal oxide composite materials and has good application prospects.