Variations and similarities in structural, chemical, and elemental properties on the ashes derived from the coal due to their combustion in open and controlled manner.

ABSTRACT

Coal fly ash (CFA) and coal-based incense sticks ash (ISA) have several similarities and differences due to the presence of coal as a common component in both of them. CFA are produced from the combustion of pulverized coal during electricity production in the thermal power plants while ISA are produced from the burning of incense sticks at religious places and at houses. A typical black colored Indian, incense sticks are mainly are comprised of coal powder or potassium nitrate, wood chip, fragrance, binder or binding agent, and bamboo sticks. The black colored incense sticks have coal powder or charcoal as a facilitator for smoother burning of incense sticks. The detailed investigation of CFA and ISA by X-ray fluorescence spectroscopy (XRF), electron diffraction spectroscopy (EDS), inductively coupled plasma-atomic emission spectroscopy (ICP-AES), Fourier transform-infrared (FTIR), X-ray diffraction (XRD), particle size analyzer (PSA), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) revealed the morphological, chemical, and elemental properties. Both the coal based ashes comprises minerals like calcites, silicates, ferrous, alumina, and traces of Mg, Na, K, P, Ti, and numerous toxic heavy metals as confirmed by the XRF, ICP-AES, and EDS. While, microscopy revealed the presence of well-organized spherical shaped particles, namely cenospheres, plerospheres, and ferrospheres of size varying from 0.02 µm to 7 microns in CFA. Whereas, ISA particles are irregular, aggregated, calcium to carbon rich whose size varies from 60 nm to 9 microns and absence of well-organized spherical structures. The well developed and crystalline structure in CFA is due to the controlled combustion parameter in thermal power plants during the burning of coal while incense sticks (IS) burning is under uncontrolled manner. So, FTIR and XRD confirmed that the major portion of fly ash constitutes crystalline minerals whereas ISA have mainly amorphous phase minerals. CFA have ferrospheres of both rough and smooth surfaced, which was absent from the ISA and hence ferrous particles of CFA are of high magnetic strength. The detailed investigation of ashes will lead to the applications of ashes in new fields, which will minimize the solid waste pollution in the environment.