Selective mono-de-O-acetylation of the per-O-acetylated brasilicardin carbohydrate side chain.
Carbohydr Res
; 504: 108312, 2021 Jun.
Article
en En
| MEDLINE
| ID: mdl-33895608
ABSTRACT
Methanol dried over powdered 4 Å molecular sieves can be used for a selective mono-de-O-acetylation of the phenolic acetyl group of the per-O-acetyl protected brasilicardin A carbohydrate side chain. This reaction opens a practical procedure for a synthetic access to derivates of the immunosuppressive and cytotoxic natural product brasilicardin A.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Carbohidratos
País/Región como asunto:
America do sul
/
Brasil
Idioma:
En
Revista:
Carbohydr Res
Año:
2021
Tipo del documento:
Article