Photoinduced Oxidative Alkoxycarbonylation of Alkenes with Alkyl Formates.

Tang, Wan-Ying; Chen, Ling; Zheng, Ming; Zhan, Le-Wu; Hou, Jing; Li, Bin-Dong

Tang, Wan-Ying; Chen, Ling; Zheng, Ming; Zhan, Le-Wu; Hou, Jing; Li, Bin-Dong.

Afiliación

Tang WY; College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Chen L; College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Zheng M; College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Zhan LW; College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Hou J; College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Li BD; College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.

Org Lett ; 23(10): 3939-3943, 2021 May 21.

Article en En | MEDLINE | ID: mdl-33974437

ABSTRACT

ABSTRACT

A photoinduced oxidative alkoxycarbonylation of alkenes initiated by intermolecular addition of alkoxycarbonyl radicals has been demonstrated. Employing alkyl formates as alkoxycarbonyl radical sources, a range of α,ß-unsaturated esters were obtained with good regioselectivity and E selectivity under ambient conditions.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2021 Tipo del documento: Article País de afiliación: China Pais de publicación: EEUU / ESTADOS UNIDOS / ESTADOS UNIDOS DA AMERICA / EUA / UNITED STATES / UNITED STATES OF AMERICA / US / USA

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