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Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field.
Kawasaki, Tsuneomi; Kaimori, Yoshiyasu; Shimada, Seiya; Hara, Natsuki; Sato, Susumu; Suzuki, Kenta; Asahi, Toru; Matsumoto, Arimasa; Soai, Kenso.
Afiliación
  • Kawasaki T; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. soai@rs.kagu.tus.ac.jp.
  • Kaimori Y; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. soai@rs.kagu.tus.ac.jp.
  • Shimada S; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. soai@rs.kagu.tus.ac.jp.
  • Hara N; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. soai@rs.kagu.tus.ac.jp.
  • Sato S; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. soai@rs.kagu.tus.ac.jp.
  • Suzuki K; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. soai@rs.kagu.tus.ac.jp.
  • Asahi T; Department of Life Science and Medical Bioscience, Waseda University (TWIns), Wakamatsu-cho, Shinjuku-ku, Tokyo 162-8480, Japan.
  • Matsumoto A; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. soai@rs.kagu.tus.ac.jp.
  • Soai K; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. soai@rs.kagu.tus.ac.jp and Research Organization for Nano & Life Innovation, Waseda University, Wasedatsurumaki-cho, Shinjuku-ku, Tokyo, 162-0041, Japan.
Chem Commun (Camb) ; 57(49): 5999-6002, 2021 Jun 17.
Article en En | MEDLINE | ID: mdl-34023863
ABSTRACT
Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e., the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: Japón
Texto completo
Añadir a Mi BVS
Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: Japón