Intermediate snapshots of a 116-nuclear metallosupramolecular cage-of-cage in a homogeneous single-crystal-to-single-crystal transformation.

Wahyudianto, Benny; Imanishi, Kento; Kojima, Tatsuhiro; Yoshinari, Nobuto; Konno, Takumi

Wahyudianto, Benny; Imanishi, Kento; Kojima, Tatsuhiro; Yoshinari, Nobuto; Konno, Takumi.

Afiliación

Wahyudianto B; Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. pkonno@chem.sci.osaka-u.ac.jp.
Imanishi K; Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. pkonno@chem.sci.osaka-u.ac.jp.
Kojima T; Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. pkonno@chem.sci.osaka-u.ac.jp.
Yoshinari N; Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. pkonno@chem.sci.osaka-u.ac.jp.
Konno T; Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. pkonno@chem.sci.osaka-u.ac.jp.

Chem Commun (Camb) ; 57(49): 6090-6093, 2021 Jun 17.

Article en En | MEDLINE | ID: mdl-34037636

ABSTRACT

ABSTRACT

Soaking crystals of an AuI72CdII40NaI4 cage-of-cage in aqueous Co(NO3)2 afforded an analogous AuI72CoII44 cage-of-cage, accompanied by the exchange of NaI and CdII by CoII with retention of the single crystallinity. The homogeneous progress of the transformation led to the direct observation of intermediate species by single-crystal X-ray crystallography.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: Japón

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