Pomegranate-like Core-Shell Ni-NSs@MSNSs as a High Activity, Good Stability, Rapid Magnetic Separation, and Multiple Recyclability Nanocatalyst for DCPD Hydrogenation.

ABSTRACT

A novel pomegranate-like Ni-NSs@MSNSs nanocatalyst was successfully synthesized via a modified Stöber method, and its application in the hydrogenation of dicyclopentadiene (DCPD) was firstly reported. The Ni-NSs@MSNSs possessed a high specific area (658 m2/g) and mesoporous structure (1.7-3.3 nm). The reaction of hydrogenation of DCPD to endo-tetrahydrodicyclopentadiene (endo-THDCPD) was used to evaluate the catalytic performance of the prepared materials. The distinctive pomegranate-like Ni-NSs@MSNSs core-shell nanocomposite exhibited superior catalytic activity (TOF = 106.0 h-1 and STY = 112.7 g·L-1·h-1) and selectivity (98.9%) than conventional Ni-based catalysts (experimental conditions Ni/DCPD/cyclohexane = 1/100/1000 (w/w), 150 °C, and 2.5 MPa). Moreover, the Ni-NSs@MSNSs nanocatalyst could be rapidly and conveniently recycled by magnetic separation without appreciable loss. The Ni-NSs@MSNSs also exhibited excellent thermal stability (≥750 °C) and good recycling performance (without an activity and selectivity decrease in four runs). The superior application performance of the Ni-NSs@MSNSs nanocatalyst was mainly owing to its unique pomegranate-like structure and core-shell synergistic confinement effect.