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Generation of a Hetero Spin Complex from Iron(II) Iodide with Redox Active Acenaphthene-1,2-Diimine.
Yambulatov, Dmitriy S; Nikolaevskii, Stanislav A; Kiskin, Mikhail A; Kholin, Kirill V; Khrizanforov, Mikhail N; Budnikova, Yulia G; Babeshkin, Konstantin A; Efimov, Nikolay N; Goloveshkin, Alexander S; Imshennik, Vladimir K; Maksimov, Yurii V; Kadilenko, Evgeny M; Gritsan, Nina P; Eremenko, Igor L.
Afiliación
  • Yambulatov DS; N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp, 119991 Moscow, Russia.
  • Nikolaevskii SA; N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp, 119991 Moscow, Russia.
  • Kiskin MA; N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp, 119991 Moscow, Russia.
  • Kholin KV; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia.
  • Khrizanforov MN; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia.
  • Budnikova YG; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia.
  • Babeshkin KA; N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp, 119991 Moscow, Russia.
  • Efimov NN; N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp, 119991 Moscow, Russia.
  • Goloveshkin AS; Nesmeyanov Institute of Organoelement Compounds, 119991 Moscow, Russia.
  • Imshennik VK; N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygina Str. 4, 119991 Moscow, Russia.
  • Maksimov YV; N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygina Str. 4, 119991 Moscow, Russia.
  • Kadilenko EM; V.V. Voevodsky Institut of Chemical Kinetics and Combustion, SB RAS, 3 Institutskaya str., 630090 Novosibirsk, Russia.
  • Gritsan NP; Department of Natural Sciences, Novosibirsk State University, 2 Pirogova Str., 630090 Novosibirsk, Russia.
  • Eremenko IL; V.V. Voevodsky Institut of Chemical Kinetics and Combustion, SB RAS, 3 Institutskaya str., 630090 Novosibirsk, Russia.
Molecules ; 26(10)2021 May 18.
Article en En | MEDLINE | ID: mdl-34070061
ABSTRACT
The reaction of the redox active 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-BIAN) and iron(II) iodide in acetonitrile led to a new complex [(dpp-BIAN)FeIII2] (1). Molecular structure of 1 was determined by the single crystal X-ray diffraction analysis. The spin state of the iron cation in complex 1 at room temperature and the magnetic behavior of 1 in the temperature range of 2-300 K were studied using Mossbauer spectroscopy and magnetic susceptibility measurements, respectively. The neutral character of dpp-BIAN in 1 was confirmed by IR and UV spectroscopy. The electrochemistry of 1 was studied in solution and solid state using cyclic voltammetry. The generation of the radical anion form of the dpp-BIAN ligand upon reduction of 1 in a CH2Cl2 solution was monitored by EPR spectroscopy.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2021 Tipo del documento: Article País de afiliación: Rusia
Texto completo
Añadir a Mi BVS
Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2021 Tipo del documento: Article País de afiliación: Rusia