Gas-phase generation of dinuclear Au(I)-Au(II) complexes by laser desorption ionization mass spectrometry.
Eur J Mass Spectrom (Chichester)
; 27(2-4): 101-106, 2021 Apr.
Article
en En
| MEDLINE
| ID: mdl-34187348
ABSTRACT
Alkali metal chloroaurates(III) were analysed by laser desorption ionization mass spectrometry. Among a number of generated gas-phase ionic clusters, the unusual ions [MAu2Cl5]- (were M stands for Na, K, Rb, Cs) were detected. The spectra of metastable ions and quantum mechanics calculations show the presence of unprecedented Au(I)-Au(II) interactions in the clusters.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Eur J Mass Spectrom (Chichester)
Año:
2021
Tipo del documento:
Article
País de afiliación:
Polonia