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Mono-mercapto-functionalized pillar[5]arene: a host-guest complexation accelerated reversible redox dimerization.
Jin, Jianbing; Miao, Jiarong; Cheng, Chuyang.
Afiliación
  • Jin J; College of Chemistry, Sichuan University, Chengdu, 610064, China. cycheng@scu.edu.cn.
  • Miao J; College of Chemistry, Sichuan University, Chengdu, 610064, China. cycheng@scu.edu.cn.
  • Cheng C; College of Chemistry, Sichuan University, Chengdu, 610064, China. cycheng@scu.edu.cn.
Chem Commun (Camb) ; 57(64): 7950-7953, 2021 Aug 10.
Article en En | MEDLINE | ID: mdl-34286743
ABSTRACT
A mono-mercapto-functionalized pillar[5]arene and its dimer, capable of being reversibly interconverted, were successfully synthesized. Fascinatingly, a faster reversible redox conversion involving a dynamic disulfide bond was observed between their host-guest complexes compared with the hosts themselves.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: China Pais de publicación: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: China Pais de publicación: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM