Quantitative appraisal of spatiotemporal uranium distribution, quality of groundwater, and associated risks in Kapurthala, Jalandhar, and Hoshiarpur districts of northern Punjab, India.

ABSTRACT

Groundwater samples from Kapurthala (45), Jalandhar (70), and Hoshiarpur (70) districts from northern Punjab, India, were studied for seasonal variation (pre-monsoon and post-monsoon) of uranium distribution and physicochemical parameters, quality and suitability for drinking purposes, source apportionment, and health risks. The average uranium concentration (in µg L-1) in Kapurthala, Jalandhar, and Hoshiarpur districts was 12.7, 18.8, and 7.0, respectively, in pre-monsoon and 8.0, 17.3, and 5.6, respectively, in post-monsoon. In both seasons, uranium concentration was below WHO limit (30 µg L-1) in more than 90% of groundwater samples, and it was found to exhibit positive correlation majorly with TDS, EC, and total alkalinity. Principal component analysis revealed dissolution of rocks/minerals contributing to mineralization of associated aquifers in addition to some anthropogenic activities such as excessive application of fertilizers/pesticides and dumping of domestic waste followed by their seepage into the groundwater table. All groundwater samples fall in very good to good drinking groundwater quality and its quality is more improved in post-monsoon season owing to dilution of various inorganic salts during groundwater recharge in monsoon season. Average Hazard Index (HI) values due to ingestion of U, F-, and NO3- via drinking water for both adults and children were found to be marginally greater than safe limit of 1 with major contribution from F-. It is advisable to local government/public that regular monitoring of groundwater and proper management policies or strategies should be adopted followed by their implementation to control groundwater pollution in three districts.