A heavy-metal-free desulfonylative Giese-type reaction of benzothiazole sulfones under visible-light conditions.

Sengoku, Tetsuya; Ogawa, Daichi; Iwama, Haruka; Inuzuka, Toshiyasu; Yoda, Hidemi

Sengoku, Tetsuya; Ogawa, Daichi; Iwama, Haruka; Inuzuka, Toshiyasu; Yoda, Hidemi.

Afiliación

Sengoku T; Department of Applied Chemistry, Faculty of Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan. sengoku.tetsuya@shizuoka.ac.jp.
Ogawa D; Department of Applied Chemistry, Faculty of Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan. sengoku.tetsuya@shizuoka.ac.jp.
Iwama H; Department of Applied Chemistry, Faculty of Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan. sengoku.tetsuya@shizuoka.ac.jp.
Inuzuka T; Division of Instrumental Analysis, Life Science Research Center, Gifu University, 1-1 Yanagido, Gifu 501-1193, Japan.
Yoda H; Department of Applied Chemistry, Faculty of Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan. sengoku.tetsuya@shizuoka.ac.jp.

Chem Commun (Camb) ; 57(77): 9858-9861, 2021 Sep 28.

Article en En | MEDLINE | ID: mdl-34490858

RESUMEN

A visible-light-induced desulfonylative Giese-type reaction has been developed. Essential to the success is the employment of Hantzsch ester to activate benzothiazole sulfones without any heavy-metal additives. Not only benzylic benzothiazole sulfones but also alkyl ones were viable substrates and reacted with electron-deficient alkenes and a propiol amide.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Reino Unido

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