Mechanochemical syntheses of all-inorganic iodide perovskites from layered cesium titanate and bismuth (and antimony) iodide.

ABSTRACT

All-inorganic iodide perovskites were prepared by a mechanochemical reaction between a layered cesium titanate and bismuth (or antimony) triiodide under ambient conditions. The layered cesium titanate was a sacrificial template and also acted as a milling media for the formation of the perovskite nanoparticles with the size of a few nanometres.